熊仁根教授1982年本科毕业于江西大学（现南昌大学），1994年获得工学博士学位，1994至1998年先后在南京大学配位化学研究所、美国波多黎各大学、Brandies大学、波士顿学院开展博士后及访问学者研究，1999年至2006年任南京大学化学化工学院教授，现为南昌大学和东南大学教授，目前担任南昌大学国际有序物质科学研究院院长。

熊仁根教授长期耕耘并专注在分子铁电体领域，提出了分子铁电体的化学设计原理——铁电化学，从铁电物理唯象理论的知其然而不知其所以然到铁电化学行之有效的设计方法，将分子铁电体的发现从盲目寻找变为合理的化学设计。铁电化学融合了化学设计、手性化学、氟化学等，有望发展成为和化学紧密联系的一门崭新学科。迄今在Science（4篇）、J. Am. Chem. Soc.（51篇）、PNAS USA（1篇）、Angew. Chem. Int. Ed.（20篇）、Phys. Rev. Lett.（4篇）、Nat. Commun.（6篇）、Adv. Mater.（11篇）、Acc. Chem. Res.（1篇）、Chem. Rev.（1篇）、Chem. Soc. Rev.（5篇）等学术刊物上发表分子铁电体研究论文100余篇。2002年获得国家杰出青年基金资助，2004年获聘教育部长江学者特聘教授，并两次获得国家自然科学二等奖（1次排名第一，1次排名第二），三次获得教育部自然科学一等奖（2次排名第一，1次排名第二）。

Prof. Ren-Gen Xiong (熊仁根教授)

Tel: 86-25-52090626

E-mail:xiongrg@seu.edu.cn

Education

1991-1994Ph. D. in Mechanical Lubrication Engineering, Logistical Engineering College

1985-1987M. S. in Chemistry, Yanbian University

1978-1982B. S. in Chemistry, Jiangxi University

Academic Career

2006-presentProfessor and Director of Order Matter Science Research Center, Southeast University.

1998-2006Professor, Nanjing University.

1997-1998Postdoctoral associate, Brandeis University.

1996-1997Postdoctoral associate, University of Puerto Rico.

1994-1996Postdoctoral associate, Nanjing University.

Research Interests

Ferroelectrochemistry; Molecular ferroelectrics; Piezoelectrics.

Funded Projects

1. NSFC: 21991140, from 2020-01 to 2024-12.

2. NSFC: 21831004, from 2019-01 to 2023-12.

3. NSFC: 21427801, from 2015-01 to 2019-12.

4. NSFC: 91422301, from 2015-01 to 2017-12.

5. NSFC: 21290172, from 2013-01 to 2017-12.

6. NSFC: 20931002, from 2010-01 to 2013-12.

Honors and Awards

2017Second Prizes in China’s State Natural Science Award.

2004Second Prizes in China’s State Natural Science Award.

2015First Prize in Natural Science of the Ministry of Education.

2002First Prize in Natural Science of the Ministry of Education

2004Cheung Kong Scholar Professor.

2015Jiangsu Province May 1 Labor Medal.

2005National Excellent Postdoctoral Fellow.

Selected Publications

1. Ai, Y.; Li, P.-F.; Yang, M.-J.; Xu, Y.-Q.; Li, M.-Z.; Xiong, R.-G.* "An organic plastic ferroelectric with high Curie point", Chem. Sci.2022, 13 (3), 748-753.

2. Liao, W.-Q.; Zeng, Y.-L.; Tang, Y.-Y.; Peng, H.; Liu, J.-C.; Xiong, R.-G.* "Multichannel Control of Multiferroicity in Single-Component Homochiral Organic Crystals", J. Am. Chem. Soc. 2021, 143 (51), 21685-21693.

3. Ai, Y.; Sun, R.; Zeng, Y.-L.; Liu, J.-C.; Tang, Y.-Y.; Wang, B.-W.; Wang, Z.-M.; Gao, S.*; Xiong, R.-G.* "Coexistence of magnetic and electric orderings in a divalent Cr²⁺-based multiaxial molecular ferroelectric", Chem. Sci.2021, 12 (28), 9742-9747.

4. Ai, Y.; Lv, H.-P.; Wang, Z.-X.*; Liao, W.-Q.; Xiong, R.-G.* "H/F substitution for advanced molecular ferroelectrics", Trends Chem.2021, 3 (12), 1088-1099.

5. Liao, W.-Q.*; Deng, B.-B.; Wang, Z.-X.*; Cheng, T.-T.; Hu, Y.-T.; Cheng, S.-P.; Xiong, R.-G.* "Optically Induced Ferroelectric Polarization Switching in a Molecular Ferroelectric with Reversible Photoisomerization", Adv. Sci.2021, 8 (24), 2102614.

6. Tang, Y.-Y.*; Liu, J.-C.; Zeng, Y.-L.; Peng, H.; Huang, X.-Q.; Yang, M.-J.; Xiong, R.-G.* "Optical Control of Polarization Switching in a Single-Component Organic Ferroelectric Crystal", J. Am. Chem. Soc.2021, 143 (34), 13816-13823.

7. Huang, C.-R.; Li, Y.*; Xie, Y.; Du, Y.; Peng, H.; Zeng, Y.-L.; Liu, J.-C.; Xiong, R.-G.* "The First High-Temperature Supramolecular Radical Ferroics", Angew. Chem. Int. Ed.2021, 60 (30), 16668-16673.

8. Zhang, H.-Y.; Chen, X.-G.; Tang, Y.-Y.*; Liao, W.-Q.; Di, F.-F.; Mu, X.; Peng, H.; Xiong, R.-G.* "PFM (piezoresponse force microscopy)-aided design for molecular ferroelectrics", Chem. Soc. Rev.2021, 50 (14), 8248-8278.

9. Song, X.-J.; Zhang, T.; Gu, Z.-X.; Zhang, Z.-X.; Fu, D.-W.*; Chen, X.-G.; Zhang, H.-Y.; Xiong, R.-G.* "Record Enhancement of Curie Temperature in Host-Guest Inclusion Ferroelectrics", J. Am. Chem. Soc. 2021, 143 (13), 5091-5098.

10. Zhang, H.-Y.; Zhang, Z.-X.; Chen, X.-G.; Song, X.-J.; Zhang, Y.; Xiong, R.-G.* "Large Electrostrictive Coefficient in a Two-Dimensional Hybrid Perovskite Ferroelectric", J. Am. Chem. Soc.2021, 143 (3), 1664-1672.

11. Huang, C.-R.; Luo, X.-Z.*; Chen, X.-G.; Song, X.-J.; Zhang, Z.-X.; Xiong, R.-G.* "A multiaxial lead-free two-dimensional organic-inorganic perovskite ferroelectric", Natl. Sci. Rev.2021, 8 (5), nwaa232.

12. Tang, Y.-Y.*; Xie, Y.; Ai, Y.; Liao, W.-Q.; Li, P.-F.; Nakamura, T.; Xiong, R.-G.* "Organic Ferroelectric Vortex-Antivortex Domain Structure", J. Am. Chem. Soc.2020, 142 (52), 21932-21937.

13. Zhang, H.-Y.; Zhang, Z.-X.; Song, X.-J.; Chen, X.-G.; Xiong, R.-G.* "Two-Dimensional Hybrid Perovskite Ferroelectric Induced by Perfluorinated Substitution", J. Am. Chem. Soc.2020, 142 (47), 20208-20215.

14. Zhang, H.-Y.*; Chen, X.-G.; Zhang, Z.-X.; Song, X.-J.; Zhang, T.; Pan, Q.; Zhang, Y.; Xiong, R.-G.* "Methylphosphonium Tin Bromide: A 3D Perovskite Molecular Ferroelectric Semiconductor", Adv. Mater.2020, 32 (47), 2005213.

15. Zhang, Z.-X.; Zhang, H.-Y.*; Zhang, W.; Chen, X.-G.; Wang, H.; Xiong, R.-G.* "Organometallic-Based Hybrid Perovskite Piezoelectrics with a Narrow Band Gap", J. Am. Chem. Soc.2020, 142 (41), 17787-17794.

16. Liu, H.-Y.; Zhang, H.-Y.*; Chen, X.-G.; Xiong, R.-G.* "Molecular Design Principles for Ferroelectrics: Ferroelectrochemistry", J. Am. Chem. Soc.2020, 142 (36), 15205-15218.

17. Tang, Y.-Y.*; Xie, Y.; Zeng, Y.-L.; Liu, J.-C.; He, W.-H.; Huang, X.-Q.; Xiong, R.-G.* "Record Enhancement of Phase Transition Temperature Realized by H/F Substitution", Adv. Mater.2020, 32 (36), 2003530.

18. Chen, X.-G.; Song, X.-J.; Zhang, Z.-X.; Zhang, H.-Y.; Pan, Q.; Yao, J.; You, Y.-M.*; Xiong, R.-G.* "Confinement-Driven Ferroelectricity in a Two-Dimensional Hybrid Lead Iodide Perovskite", J. Am. Chem. Soc.2020, 142 (22), 10212-10218.

19. Song, X.-J.; Zhang, Z.-X.; Chen, X.-G.; Zhang, H.-Y.; Pan, Q.; Yao, J.; You, Y.-M.*; Xiong, R.-G.* "Bistable State of Protons for Low-Voltage Memories", J. Am. Chem. Soc.2020, 142 (19), 9000-9006.

20. Xiong, R.-G.*; Lu, S.-Q.; Zhang, Z.-X.; Cheng, H.; Li, P.-F.*; Liao, W.-Q.* "A Chiral Thermochromic Ferroelastic with Seven Physical Channel Switches", Angew. Chem. Int. Ed.2020, 59 (24), 9574-9578.

21. Zhang, H.-Y.; Song, X.-J.; Chen, X.-G.; Zhang, Z.-X.; You, Y.-M.; Tang, Y.-Y.*; Xiong, R.-G.* "Observation of Vortex Domains in a Two-Dimensional Lead Iodide Perovskite Ferroelectric", J. Am. Chem. Soc.2020, 142 (10), 4925-4931.

22. Zhang, H.-Y.; Song, X.-J.; Cheng, H.; Zeng, Y.-L.; Zhang, Y.; Li, P.-F.; Liao, W.-Q.; Xiong, R.-G.* "A Three-Dimensional Lead Halide Perovskite-Related Ferroelectric", J. Am. Chem. Soc.2020, 142 (10), 4604-4608.

23. Zhang, Y.*; Song, X.-J.; Zhang, Z.-X.; Fu, D.-W.; Xiong, R.-G.* "Piezoelectric Energy Harvesting Based on Multiaxial Ferroelectrics by Precise Molecular Design", Matter2020, 2 (3), 697-710.

24. Liu, J.-C.; Liao, W.-Q.*; Li, P.-F.*; Tang, Y.-Y.; Chen, X.-G.; Song, X.-J.; Zhang, H.-Y.; Zhang, Y.; You, Y.-M.; Xiong, R.-G.* "A Molecular Thermochromic Ferroelectric", Angew. Chem. Int. Ed.2020, 59 (9), 3495-3499.

25. Zhang, H.-Y.; Hu, C.-L.; Hu, Z.-B.; Mao, J.-G.; Song, Y.; Xiong, R.-G.* "Narrow Band Gap Observed in a Molecular Ferroelastic: Ferrocenium Tetrachloroferrate", J. Am. Chem. Soc.2020, 142 (6), 3240-3245.

26. Wei, Z.-H.; Jiang, Z.-T.; Zhang, X.-X.; Li, M.-L.; Tang, Y.-Y.; Chen, X.-G.; Cai, H.*; Xiong, R.-G.* "Rational Design of Ceramic-Like Molecular Ferroelectric by Quasi-Spherical Theory", J. Am. Chem. Soc.2020, 142 (4), 1995-2000.

27. Chen, X.-G.; Song, X.-J.; Zhang, Z.-X.; Li, P.-F.; Ge, J.-Z.; Tang, Y.-Y.; Gao, J.-X.; Zhang, W.-Y.; Fu, D.-W.*; You, Y.-M.; Xiong, R.-G.* "Two-Dimensional Layered Perovskite Ferroelectric with Giant Piezoelectric Voltage Coefficient", J. Am. Chem. Soc.2020, 142 (2), 1077-1082.

28. Shi, P.-P.; Lu, S.-Q.; Song, X.-J.; Chen, X.-G.; Liao, W.-Q.*; Li, P.-F.; Tang, Y.-Y.*; Xiong, R.-G.* "Two-Dimensional Organic-Inorganic Perovskite Ferroelectric Semiconductors with Fluorinated Aromatic Spacers", J. Am. Chem. Soc.2019, 141 (45), 18334-18340.

29. Tang, Y.-Y.*; Ai, Y.; Liao, W.-Q.; Li, P.-F.; Wang, Z.-X.; Xiong, R.-G.* "H/F‐Substitution‐Induced Homochirality for Designing High‐T_c Molecular Perovskite Ferroelectrics". Adv. Mater.2019, 31 (29), 1902163.

30. Zhang, H.-Y.; Tang, Y.-Y.; Shi, P.-P.; Xiong, R.-G.* "Toward the Targeted Design of Molecular Ferroelectrics: Modifying Molecular Symmetries and Homochirality", Acc. Chem. Res.2019, 52 (7), 1928-1938.

31. Xiong, Y.-A.; Sha, T.-T.; Pan, Q.; Song, X.-J.; Miao, S.-R.; Jing, Z.-Y.; Feng, Z.-J.; You, Y.-M.*; Xiong, R.-G.* "The First Nickel(II)-Nitrite-Based Molecular Perovskite Ferroelectric", Angew. Chem. Int. Ed.2019, 58 (26), 8857-8861.

32. Yang, C.-K.; Chen, W.-N.; Ding, Y.-T.; Wang, J.; Rao, Y.; Liao, W.-Q.*; Tang, Y.-Y.; Li, P.-F.; Wang, Z.-X.; Xiong, R.-G.* "The First Two-Dimensional Homochiral Lead Iodide Perovskite Ferroelectrics: [R- and S-1-(4-chlorophenyl)ethylammonium]₂PbI₄", Adv. Mater.2019, 31 (16), 1808088.

33. Li, P.-F.; Liao, W.-Q.; Tang, Y.-Y.; Qiao, W.; Zhao, D.*; Ai, Y.; Yao, Y.-F.*; Xiong, R.-G.* "Organic enantiomeric high-T_c ferroelectrics", Proc. Natl. Acad. Sci. USA.2019, 116 (13), 5878-5885.

34. Liao, W.-Q.; Zhao, D.; Tang, Y.-Y.; Zhang, Y.; Li, P.-F.; Shi, P.-P.; Chen, X.-G.; You, Y.-M.; Xiong, R.-G.* "A molecular perovskite solid solution with piezoelectricity stronger than lead zirconate titanate", Science2019, 363 (6432), 1206-1210.

35. Ai, Y.; Chen, X.-G.; Shi, P.-P.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Xiong, R.-G.* "Fluorine Substitution Induced High T_c of Enantiomeric Perovskite Ferroelectrics: (R)- and (S)-3-(Fluoropyrrolidinium)MnCl₃", J. Am. Chem. Soc.2019, 141 (10), 4474-4479.

36. Wang, Z.-X.; Zhang, Y.; Tang, Y.-Y.; Li, P.-F.; Xiong, R.-G.* "Fluoridation Achieved Antiperovskite Molecular Ferroelectric in [(CH₃)₂(F-CH₂CH₂)NH]₃(CdCl₃)(CdCl₄)", J. Am. Chem. Soc.2019, 141 (10), 4372-4378.

37. Yang, C.-K.; Chen, W.-N.; Ding, Y.-T.; Wang, J.; Rao, Y.; Liao, W.-Q.; Xie, Y.*; Zou, W.*; Xiong, R.-G.* "Directional Intermolecular Interactions for Precise Molecular Design of a High-T_c Multiaxial Molecular Ferroelectric", J. Am. Chem. Soc.2019, 141 (4), 1781-1787.

38. Hua, X.-Ni.; Liao, W.-Q.*; Tang, Y.-Y.; Li, P.-F.; Shi, P.-P.; Zhao, D.; Xiong, R.-G.* "A Room-Temperature Hybrid Lead Iodide Perovskite Ferroelectric", J. Am. Chem. Soc.2018, 140 (38), 12296-12302.

39. Li, P.-F.; Tang, Y.-Y.; Liao, W.-Q.; Shi, P.-P.; Hua, X.-N.; Zhang, Y.; Wei, Z.; Cai, H.; Xiong, R.-G.* "Experimental Evidence for a Triboluminescent Antiperovskite Ferroelectric: Tris(trimethylammonium) catena-Tri--chloromanganate(II) Tetrachloromanganate(II)", Angew. Chem. Int. Ed.2018, 57 (37), 11939-11942.

40. Ye, H.-Y.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Gao, J.-X.; Hua, X.-N.; Cai, H.; Shi, P.-P.; You, Y.-M.*; Xiong, R.-G.* "Metal-free three-dimensional perovskite ferroelectrics", Science2018, 361 (6398), 151-155.

41. Wei, Z.; Liao, W.-Q.; Tang, Y.-Y.; Li, P.-F.; Shi, P.-P.; Cai, H.; Xiong, R.-G.* "Discovery of an Antiperovskite Ferroelectric in [(CH₃)₃NH]₃(MnBr₃)(MnBr₄)", J. Am. Chem. Soc.2018, 140 (26), 8110-8113.

42. Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Shi, P.-P.; You, Y.-M.; Xiong, R.-G.* "Multiaxial Molecular Ferroelectric Thin Films Bring Light to Practical Applications", J. Am. Chem. Soc.2018, 140 (26), 8051-8059.

43. Zhang, H.-Y.; Wei, Z.; Li, P.-F.; Tang, Y.-Y.; Liao, W.-Q.; Ye, H.-Y.; Cai, H.*; Xiong, R.-G.* "The Narrowest Band Gap Ever Observed in Molecular Ferroelectrics: Hexane-1,6-diammonium Pentaiodobismuth(III)", Angew. Chem. Int. Ed.2018, 57 (2), 526-530.

44. Liao, W.-Q.; Tang, Y.-Y.; Li, P.-F.; You, Y.-M.*; Xiong, R.-G.* "Large Piezoelectric Effect in a Lead-Free Molecular Ferroelectric Thin Film", J. Am. Chem. Soc.2017, 139 (49), 18071-18077.

45. Tang, Y.-Y.; Li, P.-F.; Shi, P.-P.; Zhang, W.-Y.; Wang, Z.-X.; You, Y.-M.*; Ye, H.-Y.; Nakamura, T.; Xiong, R.-G.* "Visualization of room-temperature ferroelectricity and polarization rotation in the thin film of quinuclidinium perrhenate", Phys. Rev. Lett.2017, 119 (20), 207602.

46. Jornet-Mollá, V.; Duan, Y.; Giménez-Saiz, C.; Tang, Y.-Y.; Li, P.-F.; Romero, F. M.*; Xiong, R.-G.* "A Ferroelectric Iron(II) Spin Crossover Material", Angew. Chem. Int. Ed.2017, 56 (45), 14052-14056.

47. Tang, Y.-Y.; Li, P.-F.; Zhang, W.-Y.; Ye, H.-Y.; You, Y.-M.*; Xiong, R.-G.* "A Multiaxial Molecular Ferroelectric with Highest Curie Temperature and Fastest Polarization Switching", J. Am. Chem. Soc.2017, 139 (39), 13903-13908.

48. Zhang, W.-Y.; Tang, Y.-Y.; Li, P.-F.; Shi, P.-P.; Liao, W.-Q.; Fu, D.-W.*; Ye, H.-Y.; Zhang, Y.; Xiong, R.-G.* "Precise Molecular Design of High T_c 3D Organic-Inorganic Perovskite Ferroelectric: [MeHdabco]RbI₃ (MeHdabco = N-Methyl-1,4-diazoniabicyclo[2.2.2]octane)", J. Am. Chem. Soc.2017, 139 (31), 10897-10902.

49. Pan, Q.; Liu, Z.-B.; Zhang, H.-Y.; Zhang, W.-Y.; Tang, Y.-Y.; You, Y.-M.*; Li, P.-F.; Liao, W.-Q.; Shi, P.-P.; Ma, R.-W.; Wei, R.-Y.; Xiong, R.-G.* "A Molecular Polycrystalline Ferroelectric with Record-High Phase Transition Temperature", Adv. Mater.2017, 29 (29), 1700831.

50. Zhang, Z.; Li, P.-F.; Tang, Y.-Y.; Wilson, A.-J.; Willets, K.; Wuttig, M.*; Xiong, R.-G.*; Ren S.* "Tunable electroresistance and electro-optic effects of transparent molecular ferroelectrics", Sci. Adv.2017, 3 (8), e1701008.

51. You, Y.-M.*; Liao, W.-Q.; Zhao, D.; Ye, H.-Y.; Zhang, Y.; Zhou, Q.; Niu, X.; Wang, J.; Li, P.-F.; Fu, D.-W.; Wang, Z.; Gao, S.; Yang, K.; Liu, J.-M.; Li, J.*; Yan, Y.*; Xiong, R.-G.* "An organic-inorganic perovskite ferroelectric with large piezoelectric response", Science2017, 357 (6348), 306-309.

52. Li, P.-F.; Liao, W.-Q.; Tang, Y.-Y.; Ye, H.-Y.; Zhang, Y.*; Xiong, R.-G.* "Unprecedented Ferroelectric-Antiferroelectric-Paraelectric Phase Transitions Discovered in an Organic-Inorganic Hybrid Perovskite", J. Am. Chem. Soc.2017, 139 (25), 8752-8757.

53. You, Y.-M.* Tang, Y.-Y.; Li, P.-F.; Zhang, H.-Y.; Zhang, W.-Y.; ferroelectric thin-film with duodecuple rotational polarization-directions", Nat. Commun.2017, 8, 14934.

54. Pan, Q.; Liu, Z.-B.; Tang, Y.-Y.; Li, P.-F.; Ma, R.-W.; Wei, R.-Y.; Zhang, Y.; You, Y.-M.; Ye, H.-Y.*; Xiong, R.-G.* "A Three-Dimensional Molecular Perovskite Ferroelectric: (3-Ammoniopyrrolidinium)RbBr₃", J. Am. Chem. Soc.2017, 139 (11), 3954-3957.

55. Ye, H.-Y.; Liao, W.-Q.; Zhou, Q.; Zhang, Y.; Wang, J.; You, Y.-M.*; Wang, J.-Y.; Chen, Z.-N.; Li, P.-F.; Fu, D.-W.; Huang, S.-D.; Xiong, R.-G.* "Dielectric and ferroelectric sensing based on molecular recognition in Cu(1,10-phenlothroline)₂SeO₄·(diol) systems", Nat. Commun.2017, 8, 14551.

56. Shi, P.-P.; Tang, Y.-Y.; Li, P.-F.; Ye, H.-Y.*; Xiong, R.-G.* "De Novo Discovery of [Hdabco]BF₄ Molecular Ferroelectric Thin Film for Nonvolatile Low-Voltage Memories", J. Am. Chem. Soc.2017, 139 (3), 1319-1324.

57. Tang, Y.-Y.; Zhang, W.-Y.; Li, P.-F.; Ye, H.-Y.; You, Y.-M.*; Xiong, R.-G.* "Ultrafast Polarization Switching in a Biaxial Molecular Ferroelectric Thin Film: [Hdabco]ClO₄", J. Am. Chem. Soc.2016, 138 (48), 15784-15789.

58. Li, P.-F.; Tang, Y.-Y.; Wang, Z.-X.; Ye, H.-Y.*; You, Y.-M.; Xiong, R.-G.* "Anomalously rotary polarization discovered in homochiral organic ferroelectrics", Nat. Commun.2016, 7, 13635.

59. Liao, W.-Q.; Zhao, D.*; Yu, Y.; Grice, C. R.; Wang, C.; Cimaroli, A. J.; Schulz, P.; Meng, W.; Zhu, K.; Xiong, R.-G.*; Yan, Y.* "Lead-Free Inverted Planar Formamidinium Tin Triiodide Perovskite Solar Cells Achieving Power Conversion Efficiencies up to 6.22%", Adv. Mater.2016, 28 (42), 9333-9340.

60. Ye, H.-Y.*; Ge, J.-Z.; Tang, Y.-Y.; Li, P.-F.; Zhang, Y.; You, Y.-M.*; Xiong, R.-G.* "Molecular Ferroelectric with Most Equivalent Polarization Directions Induced by the Plastic Phase Transition", J. Am. Chem. Soc.2016, 138 (40), 13175-13178.

61. Liao, W.; Zhao, D.*; Yu, Y.; Shrestha, N.; Ghimire, K.; Grice, C. R.; Wang, C.; Xiao, Y.; Cimaroli, A. J.; Ellingson, R. J.; Podraza, N. J.; Zhu, K.; Xiong, R.-G.*; Yan, Y.* "Fabrication of Efficient Low-Bandgap Perovskite Solar Cells by Combining Formamidinium Tin Iodide with Methylammonium Lead Iodide", J. Am. Chem. Soc.2016, 138 (38), 12360-12363.

62. Ye, H.-Y.; Liao, W.-Q.; Hu, C.-L.; Zhang, Y.; You, Y.-M.*; Mao, J.-G.; Li, P.-F.; Xiong, R.-G.* "Bandgap Engineering of Lead-Halide Perovskite-Type Ferroelectrics", Adv. Mater.2016, 28 (13), 2579-2586.

63. Shi, P.-P.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Wang, Z.-X.; Ye, Q.; Xiong, R.-G.* "Symmetry breaking in molecular ferroelectrics", Chem. Soc. Rev.2016, 45 (14), 3811-3827.

64. Ye, H.-Y.; Zhou, Q.; Niu, X.; Liao, W.-Q.; Fu, D.-W.; Zhang, Y.; You, Y.-M.*; Wang, J.*; Chen, Z.-N.; Xiong, R.-G.* "High-Temperature Ferroelectricity and Photoluminescence in a Hybrid Organic-Inorganic Compound: (3-Pyrrolinium)MnCl₃", J. Am. Chem. Soc.2015, 137 (40), 13148-13154.

65. Wu, J.; Fan, C.; Xue, G.; Ye, T.; Liu, S.; Lin, R.; Chen, H.; Xin, H.-L.; Xiong, R.-G.*; Li, H.* "Interfacing Solution-Grown C-60 and (3-Pyrrolinium)(CdCl₃) Single Crystals for High-Mobility Transistor-Based Memory Devices", Adv. Mater.2015, 27 (30), 4476-4480.

66. Zhang, Y.; Liao, W.-Q.; Fu, D.-W.; Ye, H.-Y.; Liu, C.-M.; Chen, Z.-N.; Xiong, R.-G.* "The First Organic-Inorganic Hybrid Luminescent Multiferroic: (Pyrrolidinium)MnBr₃", Adv. Mater.2015, 27 (26), 3942-3946.

67. Liao, W.-Q.; Zhang, Y.; Hu, C.-L.; Mao, J.-G.; Ye, H.-Y.; Li, P.-F.; Huang, S. D.; Xiong, R.-G.* "A lead-halide perovskite molecular ferroelectric semiconductor", Nat. Commun.2015, 6, 7338.

68. Zhang, Y.; Liao, W.-Q.; Fu, D.-W.; Ye, H.-Y.; Chen, Z.-N.; Xiong, R.-G.* "Highly Efficient Red-Light Emission in An Organic-Inorganic Hybrid Ferroelectric: (Pyrrolidinium)MnCl₃", J. Am. Chem. Soc.2015, 137 (15), 4928-4931.

69. Ye, H.-Y.; Zhang, Y.; Fu, D.-W.; Xiong, R.-G.* "An Above-Room-Temperature Ferroelectric Organo-Metal Halide Perovskite: (3-Pyrrolinium)(CdCl₃)", Angew. Chem. Int. Ed.2014, 53 (42), 11242-11247.

70. Ye, H.-Y.; Li, S.-H.; Zhang, Y.; Zhou, L.; Deng, F.; Xiong, R.-G.* "Solid State Molecular Dynamic Investigation of An Inclusion Ferroelectric: [(2,6-Diisopropylanilinium) ([18]crown-6)]BF₄", J. Am. Chem. Soc.2014, 136 (28), 10033-10040.

71. Zhang, Y.; Ye, H.-Y.; Cai, H.-L.; Fu, D.-W.; Ye, Q.; Zhang, W.; Zhou, Q.; Wang, J.; Yuan, G.-L.; Xiong, R.-G.* "Switchable Dielectric, Piezoelectric, and Second-Harmonic Generation Bistability in a New Improper Ferroelectric above Room Temperature", Adv. Mater.2014, 26 (26), 4515-4516.

72. Ye, H.-Y.; Zhang, Y.; Fu, D.-W.; Xiong, R.-G.* "A Displacive-Type Metal Crown Ether Ferroelectric Compound: Ca(NO₃)₂(15-crown-5)", Angew. Chem. Int. Ed.2014, 53 (26), 6724-6729.

73. Zhang, Y.; Liu, Y.; Ye, H.-Y.; Fu, D.-W.; Gao, W.; Ma, H.; Liu, Z.; Liu, Y.; Zhang, W.; Li, J.; Yuan, G.-L.*; Xiong, R.-G.* "A Molecular Ferroelectric Thin Film of Imidazolium Perchlorate That Shows Superior Electromechanical Coupling", Angew. Chem. Int. Ed.2014, 53 (20), 5064-5068.

74. Zhang, Y.; Ye, H.-Y.; Fu, D.-W.; Xiong, R.-G.* "An Order-Disorder Ferroelectric Host-Guest Inclusion Compound", Angew. Chem. Int. Ed.2014, 53 (8), 2114-2118.

75. Fu, D.-W.; Cai, H.-L.; Li, S.-H.; Ye, Q.; Zhou, L.; Zhang, W.; Zhang, Y.; Deng, F.; Xiong, R.-G.* "4-Methoxyanilinium Perrhenate 18-Crown-6: A New Ferroelectric with Order Originating in Swinglike Motion Slowing Down", Phys. Rev. Lett.2013, 110 (25), 257601.

76. Fu, D.-W.; Cai, H.-L.; Liu, Y.; Ye, Q.; Zhang, W.; Zhang, Y.; Chen, X.-Y.; Giovannetti, G.; Capone, M.; Li, J.*; Xiong, R.-G.* "Diisopropylammonium Bromide Is a High-Temperature Molecular Ferroelectric Crystal", Science2013, 339 (6118), 425-428.

77. Zhang, W.*; Xiong, R.-G.* "Ferroelectric Metal Organic Frameworks", Chem. Rev.2012, 112 (2), 1163-1195.

78. Zhang, Y.; Zhang, W.*; Li, S.-H.*; Ye, Q.; Cai, H.-L.; Deng, F.*; Xiong, R.-G.*; Huang, S. D. "Ferroelectricity Induced by Ordering of Twisting Motion in a Molecular Rotor", J. Am. Chem. Soc.2012, 134 (26), 11044-11049.

79. Cai, H.-L.; Zhang, Y.; Fu, D.-W.; Zhang, W.; Liu, T.; Yoshikawa, H.; Awaga, K.; Xiong, R.-G.* "Above-Room-Temperature Magnetodielectric Coupling in a Possible Molecule-Based Multiferroic: Triethylmethylammonium Tetrabromoferrate(III)", J. Am. Chem. Soc.2012, 134 (45), 18487-18490.

80. Cai,H.-L.; Fu,D.-W.; Zhang,Y.; Zhang,W.; Xiong,R.-G.* "Comment on "Ferroelectric Order of Parallel Bistable Hydrogen Bonds", Phys. Rev. Lett.2012, 109 (15), 169601.

81. Fu, D.-W.; Zhang, W.*; Cai, H.-L.; Ge, J.-Z.; Zhang, Y.; Xiong, R.-G.* "Diisopropylammonium Chloride: A Ferroelectric Organic Salt with Highest Phase Transition Temperature and Practical Utilization Level Spontaneous Polarization", Adv. Mater.2011, 23 (47), 5658-5662.

82. Xu, G.-C.; Zhang, W.; Ma, X.-M.; Chen, Y.-H.; Zhang, L.; Cai, H.-L.; Wang, Z.-M.*; Xiong, R.-G.*; Gao S.* "Coexistence of Magnetic and Electric Orderings in the Metal-Formate Frameworks of [NH₄][M(HCOO)₃]", J. Am. Chem. Soc.2011, 133 (38), 14948-14951.

83. Cai, H.-L.; Zhang, W.*; Ge, J.-Z.; Zhang, Y.; Awaga, K.; Nakamura, T.; Xiong, R.-G.* "4-(cyanomethyl)anilinium Perchlorate: A New Displacive-Type Molecular Ferroelectric", Phys. Rev. Lett.2011, 107 (14), 147601.

84. Fu, D.-W.; Zhang, W.*; Cai, H.-L.; Zhang, Y.; Ge, J.-Z.; Xiong, R.-G.*; Huang, S. D. "Supramolecular Bola-Like Ferroelectrics: 4-Methoxyanilinium Tetrafluoroborate-18- Crown-6", J. Am. Chem. Soc.2011, 133 (32), 12780-12786.

85. Fu, D.-W.; Zhang, W.*; Cai, H.-L.; Zhang, Y.; Ge, J.-Z.; Xiong, R.-G.*; Huang, S. D.; Nakamura, T. "A Multiferroic Perdeutero Metal-Organic Framework", Angew. Chem. Int. Ed.2011, 50 (50), 11947-11951.

86. Hang, T.; Zhang, W.*; Ye, H.-Y.; Xiong, R.-G.* "Metal-organic complex ferroelectrics", Chem. Soc. Rev.2011, 40 (7), 3577-3598.

87. Zhang, W.; Ye, H.-Y.; Cai, H.-L.; Ge, J.-Z.; Xiong, R.-G.*; Huang, S. D. "Discovery of New Ferroelectrics: [H₂dbco]₂·[Cl₃]·[CuCl₃(H₂O)₂]·H₂O (dbco=1,4-Diaza-bicyclo[2.2.2]octane)",J. Am. Chem. Soc.2010, 132 (21), 7300-7302.

88. Zhang, W.*; Cai, Y.; Xiong, R.-G.*; Yoshikawa, H.; Awaga, K. "Exceptional Dielectric Phase Transitions in a Perovskite-Type Cage Compound", Angew. Chem. Int. Ed.2010, 49 (37), 6608-6610.

89. Zhang, W.; Ye, H.-Y.; Xiong, R.-G.* "Metal-organic coordination compounds for potential Ferroelectrics", Coord. Chem. Rev.2009, 253 (23-24), 2980-2997.

90. Zhang, W.; Chen, L.-Z.; Xiong, R.-G.*; Nakamura, T.; Huang, S. D. "New Ferroelectrics Based on Divalent Metal Ion Alum", J. Am. Chem. Soc.2009, 131 (35), 12544–12545.

91. Ye, H.-Y.; Fu, D.-W.; Zhang, Y.; Zhang, W.; Xiong, R.-G.*; Huang, S. D.* "Hydrogen-Bonded Ferroelectrics Based on Metal-Organic Coordination", J. Am. Chem. Soc.2009, 131 (1), 42-43.

92. Zhao, H.; Qu, Z.-R.; Ye, H.-Y.; Xiong, R.-G.* "In situ hydrothermal synthesis of tetrazole coordination polymers with interesting physical properties", Chem. Soc. Rev.2008, 37 (1), 84-100.

93. Zhang, W.; Xiong, R.-G.*; Huang, S. D.* "3D framework containing Cu₄Br₄ cubane as connecting node with strong ferroelectricity", J. Am. Chem. Soc.2008, 130 (32), 10468-10496.

94. Fu, D.-W.; Song, Y.-M.; Wang, G.-X.; Ye, Q.; Xiong, R.-G.*; Akutagawa, T.*; Nakamura, T.; Chan, P. W. H.*; Huang, S. D.* "Dielectric anisotropy of a homochiral trinuclear nickel(II) complex", J. Am. Chem. Soc.2007, 129 (17), 5346-5347.

95. Ye, Q.; Zhao, H.; Qu, Z.-R.; Fu, D.-W.; Xiong, R.-G.*; Cui, Y.-P.*; Akutagawa, T.*; Chan, P. W. H.; Nakamura, T.* "Large Anisotropy and effect of deuteration on permittivity in an olefin copper(I) complex", Angew. Chem. Int. Ed.2007, 46 (36), 6852-6856.

96. Ye, Q.; Song, Y.-M.; Wang, G.-X.; Chen, K.; Fu, D.-W.; Chan, P. W. H.*; Zhu, J.-S.; Huang, S. D.; Xiong, R.-G.* "Ferroelectric metal-organic framework with a high dielectric constant", J. Am. Chem. Soc.2006, 128 (20), 6554-6555.

97. Ye, Q.; Wang, X.-S.; Zhao, H.; Xiong, R.-G.* "Highly stable olefin-Cu(I) coordination oligomers and polymers", Chem. Soc. Rev.2005, 34 (3), 208-225.

98. Xiong, R.-G.*; Xue, X.; Zhao, H.; You, X.-Z.; Abrahams, B. F.*; Xue, Z. "Novel, acentric metal-organic coordination polymers from hydrothermal reactions involving in situ ligand synthesis", Angew. Chem. Int. Ed.2002, 41 (20), 3800-3803.

99. Xue, X.; Wang, X.-S.; Xiong, R.-G.*; You, X.-Z.; Abrahams, B. F.*; Che, C.-M.; Ju, H.-X. "A cluster rearrangement of an open cubane (Cu₄Br₄) to a prismane (Cu₆Br₆) in a copper(I)-olefin network", Angew. Chem. Int. Ed.2002, 41 (16), 2944-2946.

100. Xiong, R.-G.*; You, X.-Z.; Abrahams, B. F.; Xue, Z. L.; Che, C.-M. "Enantioseparation of racemic organic molecules by a zeolite analogue", Angew. Chem. Int. Ed.2001, 40 (23), 4422-4425.

资料来源：

https://rcmrs.fudan.edu.cn/6c/26/c25951a486438/page.htm

https://chem.seu.edu.cn/2021/0713/c34297a378024/page.psp